Operating Temperature Research Articles

TEG and TEC Battery Cooling System

Abstract: In various industries and applications, maintaining optimal operating temperatures for batteries is important to ensure performance, longevity, and safety. Traditional methods of battery cooling often involve complex and energy-intensive systems. In this paper, we propose a Thermoelectric Generator (TEG) and Thermoelectric Cooler (TEC) battery cooling system as an innovative solution to address this challenge. By harnessing the thermoelectric effect, this system offers a compact, efficient, and environmentally friendly approach to regulate battery temperatures. Through a comprehensive review of relevant literature and the design and implementation of our TEG and TEC cooling system, we explore its potential advantages and limitations. Experimental results demonstrate the system's effectiveness in maintaining desired battery temperatures while highlighting opportunities for further optimization. This research contributes to the advancement of battery cooling technology and opens avenues for future research and practical applications in various fields, including electric vehicles, renewable energy systems, and portable electronics.

All-dielectric grating-assisted absorption enhancement in a subwavelength mercury cadmium telluride layer for infrared photodetectors

Light absorption enhancement in a 1.5 μm thick mercury–cadmium–telluride (Hg0.762Cd0.238Te, MCT) layer at room temperature utilizing 1D dielectric grating at mid-wave infrared (MWIR) wavelengths (3–5 μm) has been theoretically investigated. The optimized dielectric grating facilitates light diffraction and scattering into the MCT-absorbing waveguiding layer resulting in an increased lateral optical path. The light absorption was improved from ∼37.5% to ∼71% (TE) and ∼70% (TM) at normal incidence. With enhanced absorption, the photocarrier generation rate in the thin layer would be comparable to a bulk 5 μm thick MCT layer. A ∼3× reduction in the MCT layer thickness without compromising absorption has the potential for realizing infrared photodetectors with improved sensitivity at conventional operating temperatures and/or elevated operating temperatures.

Synthesis of indium oxide nanofibers using electrospinning method towards gas sensor application

AbstractIndium oxide nanofibers (NFs) were synthesized through a two‐step process involving electrospinning followed by calcination. The structural, microstructural, morphological, and elemental characteristics were thoroughly analyzed using techniques such as X‐ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy‐dispersive spectrometry (EDS) mapping. The characterization of the In2O3 NFs revealed their consistent thickness, structural integrity, and high purity. The nanofibers revealed a uniform diameter spanning from 20 to 50 nm. Upon subjecting the as‐spun nanofibers to heat treatment at 500 °C for 2 h, elongated In2O3 nanofibers containing necked nanoparticles were successfully obtained. The first tests of ammonia sensing were done from 250 to 450 °C; the In2O3 NFs sensor presented a good response of 2.05–100 ppm NH3 at an operation temperature of 300 °C.

Enhancement of Performance and Sulfur Tolerance of Ceria-Based Fuel Electrodes in Low Temperature SOFC

Abstract The trend of operating the solid oxide fuel cell at significantly lower operation temperatures enables the application of electrodes with finer microstructure or even nanostructured electrodes with increased active surface and enhanced performance. To maintain the high performance in hydrocarbon fuels commonly impurified with sulfur compounds, a required sulfur tolerance has to be maintained. 
In this study we compare performance and H2S-poisoning of four ceria-based electrodes: conventional Ni/Ce0.9Gd0.1O2-δ cermets and sub-µm scaled Ce0.8Gd0.2O2-δ-electrodes with and without infiltrated nickel. Symmetrical cells were operated in a hydrogen/steam/nitrogen gas mixture with and without minor amounts of H2S at 600 °C. The performance is analyzed by electrochemical impedance spectroscopy. The distribution of relaxation times is applied to deconvolute the electrochemical processes followed by a complex nonlinear least square fit to quantify the loss processes and the impact of sulfur.
Whereas two different Ni/Ce0.9Gd0.1O2-δ cermet electrodes exhibit polarization resistances at 600 °C without / with 0.1 ppm H2S of 2.89 / 5.56 Ωcm² and 2.15 / 2.75 Ωcm², the single phase Ce0.8Gd0.2O2-δ electrode reaches 0.98 / 2.37 Ωcm². With an infiltration of Ni-nitrate forming nickel nanoparticles on the gadolinia-doped ceria-surfaces, the ASR could be drastically reduced to 0.32 / 0.37 Ωcm².

Heat transport characteristics of a flat-evaporator loop heat pipe for use in a thermal management system of electric vehicles

In this work, a flat-evaporator loop heat pipe (FELHP), with a 100 cm2 rectangular thermal interface and an overall length of approximately 2 m was devised for the thermal management of electric vehicles. A simple rectangular-cuboid evaporator was devised using a novel stepped-flat wick structure, and the heat transport characteristics were systematically investigated in terms of the heat load, relative height of the evaporator to the condenser (i.e., position), heat sink temperature, and working fluid. In particular, water-ethanol binary mixtures with different compositions were tested to find an optimum low-freezing-temperature working fluid for use in thermal management system of the electric vehicles driving outdoors. Over the tested heat load range, a significant position dependence of the operating temperature was observed with a thermal resistance change from 0.21 K/W ± 0.02 K/W to 0.14 K/W ± 0.01 K/W for a 0.4 m change in the position. In contrast, the operating temperature of the FELHP was insensitive to changes in the heat sink temperature. A binary mixture containing 20% water and 80% ethanol (by volume) resulted in comparable heat transport characteristics to those of pure water but had a much lower freezing temperature (e.g., a thermal resistance of 0.25 K/W ± 0.03 K/W at 450 W and a freezing temperature of approximately -59 °C), demonstrating that this was an optimum composition of the water-ethanol mixture working fluid of the FELHP.

Integrated carbon dioxide capture and utilization for the production of CH4, syngas and olefins over dual‐function materials

The massive emission of carbon dioxide produces the greenhouse effect and poses a threat to the survival of modern civilization. The search for new carbon management strategies has been at the forefront of scientific research over the past few decades. Integrated carbon dioxide capture and utilization (ICCU), which aims to capture CO2 and convert it in situ into high value‐added products or fuels, is considered to be more attractive and innovative than alternative strategies. This paper introduces the adsorption capacity and characteristics of solid sorbents at different operating temperatures. On this basis, the recent research on ICCU technology combined with methanation, the reverse water‐gas shift reaction, dry reforming of alkanes and dehydrogenation of alkanes over novel dual function materials is presented, and the development direction and future prospects of ICCU are discussed.

Moisture reaction mechanism of Au-modified SnO2 ultrathin nanosheets with exclusive detection of formaldehyde

Exploring the reaction mechanism at the molecular level in detecting different target gases and providing the optimal operating temperature can improve selective detection performance and extend the lifetime of chemiresistors in practical sensing applications. While the humidity effect interaction mechanism between gas and sensor hinders its practical application. Therefore, exploring the reaction mechanism of humidity to detect different target gases at the molecular level can promote the development of exclusive detection performance and service life of sensors. To further disclose this, a one-step chemical method is applied to synthesize the defect-rich SnO2 with an ultrathin nanosheet structure. The experimental results confirmed that the inhibitory effect of humidity on the detection of formaldehyde by Au-SnO2 is significantly lower than that of other interfering volatile organic compounds (VOCs). The response value of Au-SnO2 detect 10 ppm of formaldehyde at 55 °C is 78, which is larger than that of methanol, ethanol, and acetone. This study sheds light on the mechanistic insight into the correlation between operating temperatures and humidity on the excellent performance of the Au-SnO2 chemiresistive sensor. We consider our work significant in developing highly efficient and stable electrochemical sensors to detect VOC gases at room temperature.

Alternative Concepts for Extruded Power Cable Insulation: from Thermosets to Thermoplastics.

The most common type of insulation of extruded high-voltage power cables is composed of low-density polyethylene (LDPE), which must be crosslinked to adjust its thermomechanical properties. A major drawback is the need for hazardous curing agents and the release of harmful curing byproducts during cable production, while the thermoset nature complicates reprocessing of the insulation material. This perspective explores recent progress in the development of alternative concepts that allow to avoid byproducts through either click chemistry type curing of polyethylene-based copolymers or the use of polyolefin blends or copolymers, which entirely removes the need for crosslinking. Moreover, polypropylene-based thermoplastic formulations enable the design of insulation materials that can withstand higher cable operating temperatures and facilitate reprocessing by remelting once the cable reaches the end of its lifetime. Finally, polyethylene-based covalent and non-covalent adaptable networks are explored, which may allow to combine the advantages of thermoset and thermoplastic insulation materials in terms of thermomechanical properties and reprocessability.

Electro‐Thermo‐Mechanical Characterization of Shape Memory Alloy Wires for Actuator and Sensor Applications – Part 2: High Ambient Temperature Behavior

The typical phase transformation temperatures of commercially available shape memory alloys (SMA) for actuator applications are in the region of 80 °C to 90 °C for austenite finish and around 60 °C for martensite start. That limits the areas of application for SMA actuators, as increased ambient temperatures restrict their functionality. Especially in the industrial and automotive sectors, operational temperatures of 80 °C and higher are commonly required. This article discusses the limits of operation temperatures for commercially available SMA actuator wires. Also, methods to increase this critical temperature limit, at which the SMA actuation strain falls below a certain threshold, are proposed. By means of electro‐thermal actuation experiments, the influence of the variation of bias loads and an additional training method are investigated. Supported by these results, an exemplary valve actuator system is designed, which exhibits consistent stroke in a wide range of ambient temperatures. All experiments and measurements are conducted on a custom designed test bench with the same commercially available SMA wire. The test bench is in the following used again to evaluate the designed SMA valve actuator.This article is protected by copyright. All rights reserved.

Thermally stable Ni foam-supported inverse CeAlOx/Ni ensemble as an active structured catalyst for CO2 hydrogenation to methane

Nickel is the most widely used inexpensive active metal center of the heterogeneous catalysts for CO2 hydrogenation to methane. However, Ni-based catalysts suffer from severe deactivation in CO2 methanation reaction due to the irreversible sintering and coke deposition caused by the inevitable localized hotspots generated during the vigorously exothermic reaction. Herein, we demonstrate the inverse CeAlOx/Ni composite constructed on the Ni-foam structure support realizes remarkable CO2 methanation catalytic activity and stability in a wide operation temperature range from 240 to 600 °C. Significantly, CeAlOx/Ni/Ni-foam catalyst maintains its initial activity after seven drastic heating-cooling cycles from RT to 240 to 600 °C. Meanwhile, the structure catalyst also shows water resistance and long-term stability under reaction condition. The promising thermal stability and water-resistance of CeAlOx/Ni/Ni-foam originate from the excellent heat and mass transport efficiency which eliminates local hotspots and the formation of Ni-foam stabilized CeAlOx/Ni inverse composites which effectively anchored the active species and prevents carbon deposition from CH4 decomposition.

Emission current enhancement from quasi-freestanding epitaxial graphene microstructure electron emitters through surface layered silicon dioxide

Abstract Enhanced electron emission from oxide-encapsulated quasi-freestanding bilayer epitaxial graphene (QFEG) devices is reported, including one emission current of 9.4 µA and successful emission even with oxide thicknesses of up to 1.25 µm. The low operating temperature (215 oC), and applied electric fields under which the devices operate indicate electron emission is due to phonon-assisted electron emission (PAEE), wherein forward-scattering hot phonons impart the necessary energy for the electrons to escape the graphene as an emission current. A suite of device structures and behaviors are cataloged, and various emission behaviors are demonstrated through encapsulating oxide layers. Emission current enhancement due to electron multiplication in the oxide layers is observed across multiple devices and oxide thicknesses.

Magnetic, Optical, Electrical and Antimicrobial Properties of MnCuZnFe2O4 Nanoparticles

AbstractThe Mn0.92Cu0.08‐yZnyFe2O4 (y=0.02, 0.04, 0.06 and 0.08) nanoparticles (MCZF NPs) were synthesized via the hydrothermal process at low operating temperature. The MCZF system generated a cubic spinel structure as seen by the X‐ray diffraction patterns. The average crystallite size was observed to be increasing from 25 to 30 nm. The broad (γ1) and narrow (γ2) absorption bands were seen in FTIR spectra and the cation distributions at tetrahedral (A) and octahedral (B) sites, respectively, was indicated. The surface morphology was analyzed using electron microscopy. Clarification was provided for the dependence of the optical bandgap shift (Eg~1.96–2.15 eV) on the concentration of substituent. The superparamagnetic nature of MCZF can be advantageous for biomedical applications and it was demonstrated by the magnetization versus applied magnetic field (M−H) loops. Small values of remanence magnetization (Mr) and coercivity (Hc) were found using magnetization versus magnetic field (M−H) curves at y=0.02, 0.04, 0.06, and 0.08. This proved that MCZF NPs exhibited the superparamagnetic behavior. The cation distribution at two sublattices was also estimated using a two‐sublattice model. The greatest zone of inhibition in an antibacterial study of MCZF (produced by the green method) was 10.8 mm for Pseudomonosa aeruginosa and 9.4 mm for Staphylococcus aureus.

Analysis of Power Consumption on BOP System in a Fuel Cell Electric Bus According to the Fuel Cell Load Range

AbstractThe proton exchange membrane fuel cell (PEMFC) in a fuel cell electric bus (FCEB) converts hydrogen's chemical energy into electrical energy. The fuel cell system comprises a fuel cell stack and a balance of plant (BOP) system, which efficiently controls the stack. Fuel cell and battery are sensitive to operational temperature, which directly impacts performance, lifespan, and safety. Therefore, a thermal management system (TMS) is necessary to maintain an appropriate temperature by dissipating the heat generated by the fuel cell and battery. In this study, the exponential or quadratic relationships between the power consumption of the major components of an FCEB and various factors, such as temperature and flow rate influencing the operational behavior and control of the components, were analyzed based on the results of a dynamometer vehicle test. Additionally, the vehicle's energy flow was calculated under different fuel cell load conditions. When the fuel cell operated at 56.3 kW, TMS power was 6.6 times higher than at 20 kW. At full load, under 90 kW, it increased to 17.4 times higher. The rise in fuel cell load correlated with higher heat generation, resulting in a significant increase in power consumption for both the radiator fan and coolant pump.

Strain-induced high-Chern-number spin-unlocked edge states in monolayer MnAsO3 with intrinsic quantum anomalous Hall effect

Two-dimensional intrinsic magnetic topological materials that can realize device miniaturization have attracted significant attention recently based on their chiral dissipationless edge states. However, since the experimental observation of quantum anomalous Hall effect (QAHE) is still limited by low temperature, high operating temperature and large nontrivial gap are urgently needed. Here, monolayer MnAsO3 is predicted to be a room-temperature intrinsic magnetic topological material with high Chern number C = 3 based on first-principles calculations, which offers the possibility of achieving high-speed and low-energy-consumption electron transport in the future. Furthermore, the large and experimental feasible nontrivial gap up to 79.09 meV is obtained under compressive strain modulation. Moreover, the high-Chern-number topological phase transition and strain-induced spin-unlocked edge states are observed, indicating the possibility of tuning the electron transport of QAHE. All these findings suggest that monolayer MnAsO3 is a suitable and promising material for fabricating low-energy-consumption spintronics devices.

Mussel-Inspired Self-Adhesive and Tough Hydrogels for Effectively Cooling Solar Cells and Thermoelectric Generators.

Adhesive hydrogel-based evaporative cooling, which necessitates no electricity input, holds promise for reducing energy consumption in thermal management. Herein, inspired by the surface attachment of mussel adhesive proteins via abundant dynamic covalent bonds and noncovalent interactions, we propose a facile strategy to fabricate a self-adhesive cooling hydrogel (Li-AA-TA-PAM) using a copolymer of acrylamide (AM) and acrylic acid (AA) as the primary framework. The monomers formed hydrogen bonds between their carboxyl and amide groups, while tannic acid (TA), rich in catechol groups, enhances the adhesion of the hydrogel through hydrogen bonding. The hydrogel demonstrated strong adhesion to various material surfaces, including plastic, ceramic, glass, and metal. Even under high-speed rotation, it still maintains robust adhesion. The adhesion strength of the Li-AA-TA-PAM hydrogel to aluminum foil reached an impressive value of 296.875 kPa. Interestingly, the excellent contact caused by robust adhesion accelerates heat transfer, resulting in a rapid cooling performance, which mimics the perspiration of mammals. Lithium bromide (LiBr) with hydroactively sorptive sites is introduced to enhance sorption kinetics, thereby extending the effective cooling period. Consequently, the operation temperature of commercial polycrystalline silicon solar cells was reduced by 16 °C under an illumination of 1 kW m-2, and the corresponding efficiency of energy conversion was increased by 1.14%, thereby enhancing the output properties and life span of solar cells. The strategy demonstrates the potential for refrigeration applications using viscous gels.

Highly Sensitive and Selective Toluene Gas Sensors Based on ZnO Nanoflowers Decorated with Bimetallic AuPt.

Efficient sensors for toluene detecting are urgently needed to meet people's growing demands for both environment and personal health. Metal oxide semiconductor (MOS)-based sensors have become brilliant candidates for the detection of toluene because of their superior performance over gas sensing. However, gas sensors based on pure MOS have certain limitations in selectivity, operating temperature, and long-term stability, which hinders their further practical applications. Noble metals (including Ag, Au, Pt, Pd, etc.) have the ability to enhance the performance of MOS-based sensors via surface functionalization. Herein, ZnO nanoflowers (ZNFs) modified with bimetallic AuPt are prepared for toluene detection through hydrothermal method. The response of a AuPt@ZNF-based gas sensor can reach 69.7 at 175 °C, which is 30 times, 9 times, and 10 times higher than that of the original ZNFs, Au@ZNFs, and Pt@ZNFs, respectively. Furthermore, the sensor also has a lower optimal operating temperature (175 °C), good stability (94% of previous response after one month), and high selectivity towards toluene, which is the result of the combined influence of the electronic and chemical sensitization of noble metals, as well as the unique synergistic effect of the AuPt alloy. In summary, AuPt@ZNF-based sensors can be further applied in toluene detection in practical applications.

Perovskite for Electrocatalytic Oxygen Evolution at Elevated Temperatures.

The development of advanced electrolysis technologies such as anion exchange membrane water electrolyzer (AEMWE) is central to the vision of a sustainable energy future. Key to the realization of such AEMWE technology lies in the exploration of low-cost and high-efficient catalysts for facilitating the anodic oxygen evolution reaction (OER). Despite tremendous efforts in the fundamental research, most of today's OER works are conducted under room temperature, which deviates significantly with AEMWE's operating temperature (50-80 °C). To bridge this gap, it is highly desirable to obtain insights into the OER catalytic behavior at elevated temperatures. Herein, using the well-known perovskite catalyst Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) as a proof of concept, the effect of temperature on the variation in OER catalytic activity and stability is evaluated. It is found that the BSCF's activity increases with increasing temperature due to enhanced lattice oxygen participation promoting the lattice oxygen-mediated OER process. Further, surface amorphization and cation leaching of BSCF become more pronounced as temperature increases, causing a somewhat attenuated OER stability. These new understandings of the fundamental OER catalysis over perovskite materials at industrial-relevant temperature conditions are expected to have strong implications for the research of OER catalysts to be deployed in practical water electrolyzers.

Multi Phase Driven Large Operating Temperature Range Magnetocaloric Effect in In Incorporated HoCo2 Alloy

Multi Phase Driven Large Operating Temperature Range Magnetocaloric Effect in In Incorporated HoCo2 Alloy

Deterministic and probabilistic occupant-centric control's impacts on the indoor environment in free-running households

PurposeOccupant behavior can lead to considerable uncertainties in thermal comfort and air quality within buildings. To tackle this challenge, the use of probabilistic controls to simulate occupant behavior has emerged as a potential solution. This study seeks to analyze the performance of free-running households by examining adaptive thermal comfort and CO2 concentration, both crucial variables in indoor air quality. The investigation of indoor environment dynamics caused by the occupants' behavior, especially after the COVID-19 pandemic, became increasingly important. Specifically, it investigates 13 distinct window and shading control strategies in courtyard houses to identify the factors that prompt occupants to interact with shading and windows and determine which control approach effectively minimizes the performance gap.Design/methodology/approachThis paper compares commonly used deterministic and probabilistic control functions and their effects on occupant comfort and indoor air quality in four zones surrounding a courtyard. The zones are differentiated by windows facing the courtyard. The study utilizes the energy management system (EMS) functionality of EnergyPlus within an algorithmic interface called Ladybug Tools. By modifying geometrical dimensions, orientation, window-to-wall ratio (WWR) and window operable fraction, a total of 465 cases are analyzed to identify effective control scenarios. According to the literature, these factors were selected because of their potential significant impact on occupants’ thermal comfort and indoor air quality, in addition to the natural ventilation flow rate. Additionally, the Random Forest algorithm is employed to estimate the individual impact of each control scenario on indoor thermal comfort and air quality metrics, including operative temperature and CO2 concentration.FindingsThe findings of the study confirmed that both deterministic and probabilistic window control algorithms were effective in reducing thermal discomfort hours, with reductions of 56.7 and 41.1%, respectively. Deterministic shading controls resulted in a reduction of 18.5%. Implementing the window control strategies led to a significant decrease of 87.8% in indoor CO2 concentration. The sensitivity analysis revealed that outdoor temperature exhibited the strongest positive correlation with indoor operative temperature while showing a negative correlation with indoor CO2 concentration. Furthermore, zone orientation and length were identified as the most influential design variables in achieving the desired performance outcomes.Research limitations/implicationsIt’s important to acknowledge the limitations of this study. Firstly, the potential impact of air circulation through the central zone was not considered. Secondly, the investigated control scenarios may have different impacts on air-conditioned buildings, especially when considering energy consumption. Thirdly, the study heavily relied on simulation tools and algorithms, which may limit its real-world applicability. The accuracy of the simulations depends on the quality of the input data and the assumptions made in the models. Fourthly, the case study is hypothetical in nature to be able to compare different control scenarios and their implications. Lastly, the comparative analysis was limited to a specific climate, which may restrict the generalizability of the findings in different climates.Originality/valueOccupant behavior represents a significant source of uncertainty, particularly during the early stages of design. This study aims to offer a comparative analysis of various deterministic and probabilistic control scenarios that are based on occupant behavior. The study evaluates the effectiveness and validity of these proposed control scenarios, providing valuable insights for design decision-making.

Reusable Cell Design for High-Temperature (600°C) Liquid Metal Battery Cycling

Abstract This paper presents the cycling of a novel low-cost Na-Zn liquid metal battery. Its 600°C operating temperature presents multiple challenges that must be overcome to achieve commercial viability, both from a structural and electrochemical perspective. To enable long-term cycling of the Na-Zn battery in realistic environment, we have developed a reusable, hermetically sealed, high temperature and sufficiently corrosion resistant cell concept. The design as well as various approaches for assembling and filling the cell are presented. The factors considered when selecting specific components are documented and explained. The active volume of the cell design can be up to 40 mL, corresponding to a nominal capacity of 1 A h, while the entire cell body weighs around 800 g and costs approximately €200 ($215). The performance of the cell is demonstrated in terms of longevity (1000 h) and high discharge current density (100 mA m-2). The manuscript not only presents the first long-term cycling performance of the novel Na-Zn chemistry achieving Coulombic efficiency of up to 80%, but also demonstrates the design's versatility with in situ dynamic neutron radiography of the cell.